preprint · ChemRxiv
A matched quintet bis-quinoline tricarbonyl complex was synthesized across Group 6/7 transition metals (M = Cr, Mo, W, Mn, Re). The complexes display trends in structure and bonding, observed by X-ray crystallography, NMR, Infrared, UV-Vis and fluorescence. Biological testing reveals high activity for Group 7 complexes against Gram-positive bacteria. Post-synthetic functionalisation with Click chemistry was explored.
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DOI: 10.26434/chemrxiv.15007450/v1
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