Synthesis and Characterization of SnO₂/α-Fe₂O₃, In₂O₃/α-Fe₂O₃, and ZnO/α-Fe₂O₃ Thin Films: Photocatalytic and Antibacterial Applications

Abstract

The fabrication of metal oxide semiconductor heterostructures is a major way to enhance their properties in photocatalytic and antibacterial applications. In the present work, ZnO/α-Fe2O3, In2O3/α-Fe2O3, and SnO2/α-Fe2O3 are chosen to create the heterostructure of thin films using the spray pyrolysis method. This paper compares the experimental results of the structural and morphological properties of the prepared thin layers using XRD, Raman and SEM. The X-ray diffraction shows that the obtained thin film heterostructures crystallize in a hexagonal phase of ZnO, a cubic phase of In2O3 and a tetragonal structure of SnO2, with all of the preceding phases positioned on the rhombohedral phase of the hematite α-Fe2O3. In addition, the SEM study provided the morphology and surface structure and confirmed the presence of a highly folded, rough, uneven surface with imperfections of 20 and 65 nm for In2O3/α-Fe2O3 and SnO2/α-Fe2O3. The photoactivity of the prepared materials was tested via the photocatalytic degradation of methylene blue (MB) dye. Consequently, our findings demonstrate that the cracked surface improves the rapid absorption of contaminants and allows water to easily pass through the surface of the thin layers. Finally, the antibacterial abilities of ZnO/α-Fe2O3, In2O3/α-Fe2O3, and SnO2/α-Fe2O3 thin films were investigated by using the agar well-diffusion technique, comparing the results to the Gram-negative of Pseudomonas aeruginosa and Gram-positive of Bacillus subtilis, and these thin films were found to have high antibacterial activity.