Sustainable Carbon–Carbon Composites from Biomass-Derived Pitch: Optimizing Structural, Electrical, and Mechanical Properties via Catalyst Engineering

Abstract

This work is based on our previous research on sulfur-assisted graphitization of biopitch by focusing on catalyst-driven optimization of biomass-derived pitch (BDP) composites as sustainable alternatives to coal tar pitch (CTP). Biomass from eucalyptus sawdust was pyrolyzed to produce BDP, which was used as a binder for carbon–carbon composites. The properties of BDP/graphite and CTP/graphite composites, including bending strength, electrical conductivity, hardness, density, porosity, mass loss, and shrinkage, were compared. Furthermore, the influence of catalysts (NiSO4, K2SO4, CuSO4, FeSO4, and KOH) on composite performance was systematically investigated. Results show that catalyst selection significantly enhances structural, electrical, and mechanical properties, demonstrating the potential of combining eco-friendly materials with strategic catalyst engineering to develop high-performance, sustainable composites.