Reply to Comment by Terence McCarthy and Marc Humphries on “Highly Contrasted Geochemical Pattern in Sediments of the Okavango Delta, Botswana Driven by Dust Supply, Hydrological Heritage and Biogeochemical Reactions”

Abstract

Abstract In southern Africa, the Okavango Delta is a large alluvial fan sustaining a unique wetlands ecosystem in the heart of the Kalahari desert. The Delta is fed by an annual flood that brings water from the Angolan plateaus to the north, down to the Okavango region. The fan is characterized by vegetated, permanent or seasonal floodplains, dotted with thousands of sandy islands of various origin (inverted paleo‐channels, paleo‐dunes, meander bars, etc). On at least some of these islands, shallow groundwater is characterized by a high pH (>8) and a high concentration of metals and metalloids, making it naturally toxic. In the 1990s, McCarthy and co‐workers explain the chemistry of that water through an evapotranspiration model, the flood‐water being pumped by the vegetation toward the center of the islands and progressively enriched in elements by evapotranspiration. This model has been widely applied to all islands in the Okavango, not considering their individual specificities nor that of the surrounding floodplain. Our work, based on a multidisciplinary approach including sedimentology, mineralogy and geochemistry, and discussed by McCarthy and Humphries, questions the established model suggesting that the alkaline water cannot derive from simple concentration of the floodwater.