Quantifying Ageing of 35-50 and 70-100 Asphalts Using Fourier Transform Infrared Spectroscopy and Dynamic Shear Rheometer Measurements

Abstract

In this study, Dynamic Shear Rheometer (DSR) and Fourier Transform Infrared (FTIR) spectroscopy tests were performed on 35-50 and 70-100 penetration-graded asphalts. Both tests were performed on specimens at three different ageing states: unaged, short-term aged using the standard rolling thin film oven (RTFO) device, and long term aged by placing RTFO residue in the pressure aging vessel (PAV) apparatus. The tests were accomplished to quantify how ageing affects the results of both tests, namely the complex shear modulus for the DSR test and the carbonyl, sulfoxide, and ageing indices for the FTIR spectroscopy test. Both sets of measurements confirm that the harder asphalt stays harder than the softer asphalt after undergoing ageing, but the rate of hardness is higher for the softer asphalt. For instance, on average, PAV ageing was found to increase the amplitude of the shear complex modulus, from the unaged state, by 4.3 times and by 6.2 times for the 35-50 and 70-100 asphalts, respectively. It was also found that ageing decreases the phase angle for asphalt and the decrease is more pronounced for the softer asphalt (70-100) than the harder one (35-50). This was attributed to more maltenes content in the softer asphalt that transform into asphaltenes during ageing. Correlation coefficient between FTIR signals from the same samples revealed that FTIR spectroscopy as used in this research has an excellent repeatability. The repeatability was also confirmed using measures of dispersion such as the coefficient of variation, which was found not to exceed the 1.2%. The 35-50 asphalt was found to have more C=O and S=O links than the 70-100 asphalt since it showed more absorbance in the carbonyl and sulfoxide bands. These links are thought to make the asphalt physically harder. An analysis of variance study revealed that ageing is a statistically significant factor as measured using ageing indices calculated from FTIR spectroscopy data with the index AI FTIR being the most sensitive to ageing among all considered indices. Empirical power equations with high coefficient of determination values were established to predict DSR results from FTIR index values, which was possible since both types of measurements show the same trend with ageing.