Polycyclic aromatic hydrocarbons within the vicinity of a scrap-iron smelting plant: indoor-outdoor and seasonal pattern, source, and exposure risk assessment

Abstract

The growing demand for ferrous metals and abundant scrap materials has fueled Nigeria's scrap-iron smelting industry, leading to hazardous pollutant emissions. This study investigated the concentrations, seasonal and indoor-outdoor variations, origins, and health impacts of polycyclic aromatic hydrocarbons (PAHs) in dust samples around a scrap-iron smelting facility. Analyses of dust samples revealed that high molecular weight PAHs (HMWPAHs) dominated during both seasons, with 5-ring PAHs (34%) contributing most during the rainy season and 3-ring PAHs (36%) during the dry season. Carcinogenic PAHs were more prevalent in the rainy season compared to the dry season. Seven PAH sources were identified, with gasoline combustion being the dominant source during the rainy season and iron and steel production during the dry season. Incremental lifetime cancer risk (ILCR) assessments showed PAH concentrations within safe limits, with dermal contact identified as the primary exposure pathway for both children and adults in the study area.