Performance Evaluation and Microstructural Analysis of Eco-Friendly Self-Compacting Geopolymer Concrete

Abstract

The rising environmental burden of Portland cement production has intensified the demand for eco-friendly binders that support sustainable construction. This study investigates the development and performance of eco-friendly self-compacting geopolymer concrete (SCGC) produced from industrial by-products, including fly ash (FA), ground granulated blast furnace slag (GGBFS), silica fume (SF), metakaolin (MK), and glass waste powder (GWP). Twenty-one binder formulations were evaluated for fresh-state workability, mechanical performance, durability, and microstructural characteristics under different curing regimes. Fresh properties were assessed using slump flow, V-funnel, L-box, and J-ring tests, while hardened-state evaluations included compressive and flexural strength, Young’s modulus, and water absorption. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis were performed on selected mixes to examine microstructural features and crystalline phase development. Results highlight a strong dependency of SCGC performance on binder composition and curing conditions. Mixes rich in GGBFS and SF demonstrated superior mechanical and durability performance, achieving compressive strengths of up to 102.4 MPa under water curing and 107.6 MPa under heat curing, along with negligible water absorption, reflecting a dense and well-developed gel matrix. SEM micrographs confirmed homogeneous, compact microstructures in high-performing mixes, while XRD analysis revealed broad amorphous humps indicative of well-formed N-A-S-H and C-A-S-H gel phases with minimal crystalline residues. In contrast, FA-dominant mixes displayed delayed strength development, and MK-GWP-rich systems exhibited higher porosity and reduced strength. This study underscores the significance of precursor synergy, optimized curing strategies, and microstructural refinement in tailoring SCGC for high-performance, durable, and low-carbon applications in sustainable construction with values ranged from 38.64 GPa (Mix 21) to 25.04 GPa (Mix 19) at 28 days. Stiffer mixes corresponded to denser matrices containing GGBFS and silica fume, whereas lower values were linked to weaker bonding and higher porosity.