article · Catalysis Letters
Abstract In this work, the catalytic conversion of furfural was found to follow both CTHs and etherification pathways in one-pot over multicationic inorganic perovskites (LaNi 1-x Mo x O 3±δ ) as heterogeneous catalysts. The conversion of furfural (FA) into alcohols and ether functionalities using the as-synthesized perovskite catalysts showed good conversions that are above 80% and excellent selectivity towards the desired product. The LaMoO 3 catalyst was found to achieve the highest percentage conversion of 83%. Simple and multicationic inorganic perovskites were successfully employed in the transformation of furfural to produce β-methoxy-2-furanethanol. Furthermore, we postulate the hydrogenation of the keto-group to be the first step in the mechanism of the formation of β-methoxy-2-furanethanol and that its formation is characterized by rearrangement of the intermediate over the surface of the catalyst. Graphical abstract
This page summarises published work. The authoritative version sits with the publisher.
DOI: 10.1007/s10562-024-04864-y
Is something wrong with this record? Report it or request removal.
Discussion
Have you built on this work, tried to replicate it, or seen it applied in practice? Share what you know. Verified researchers and MARATTO™ domain experts can open a discussion, and any member can reply. Contributions are reviewed before they appear.
No discussion yet. Open the first thread.
New to MARATTO™? Create a free account.