Metallic nanoparticles and hybrids of metallic nanoparticles/graphene nanomaterials for enhanced photon harvesting and charge transport in polymer and dye sensitized solar cells

Abstract

Solar energy is a sustainable option in the provision of affordable and clean energy. Conversion of solar energy to electricity requires the development of materials and technologies that are not only efficient but also cost-effective. Polymer solar cells (PSCs) and dye sensitized solar cells (DSSCs) are some of the cost-effective technologies for solar energy conversion. However, PSCs suffer from poor optical absorption and charge carrier mobility, while the major drawback to high efficiencies in DSSCs is charge carrier recombination. This article examines the potency of plasmonic metallic nanoparticles (MNPs) and hybrids of MNPs/graphene nanomaterials (GNMs) in mitigating these challenges. MNPs and MNPs/GNMs incorporated in these devices enhance light harvesting to extended wavelengths and improve charge transport. MNPs in the photoanode of DSSCs serve as cosensitizers to offer complementary optical absorption, while MNPs/GNMs as counter electrode yield high catalytic activity comparable to Pt. Simultaneous application of MNPs and/or MNPs/GNMs in PSCs' interfacial and active layers yield enhanced broadband optical absorption and effective charge transport. The mechanisms by which these nanomaterials enhance light harvesting in these devices are discussed in detail. The material characteristics that influence the performance of MNPs and MNPs/GNMs modified devices, such as MNPs size, shape, and morphology, are highlighted. Hence, this article presents perspectives and strategies on successful utilization of plasmonic MNPs and hybrids of MNPs/GNMs to mitigate the challenges of poor optical absorption and charge transport of PSCs and DSSCs for high efficiencies.