Geometry, Extent, and Chemistry of Fermentative Hot Spots in Municipal Waste Souk Sebt Landfill, Ouled Nemma, Beni Mellal, Morocco

Abstract

The presence of fermentative hotspots in municipal waste dumps has been reported for several decades, but no study has focused on their size and shape. The uncontrolled landfill of Soub Sekt, covering an area of about 8 hectares in the Tadla plain in Morocco, is the source of a permanent pollution plume in the groundwater, detected by self-potential (SP) measurements. The study aims to detect and characterize these hotspots as well as the leachates that form within them. These hotspots are typically circular and smaller than 3 m in size, and they are concentrated within recent waste deposits. Intense electron transfer activities, particularly during redox reactions leading to metal solubilization, result in very low SP values (down to −60 mV), facilitating their detection. Several successive field campaigns suggest that they are active for 2–3 weeks. Due to the low permeability of the soils, highly mineralized leachates (average Electrical Conductivity 45 mS cm−1) rich in organic ions accumulate on the soil surface at the base of the waste windrows. There, they evolve by concentration due to evaporation and oxidation due to slow diffusion of atmospheric O2. Despite the small size of the hotspots generating the leachates, the accumulation of leachates in ponds and the low soil permeability limits the percolation rate, resulting in moderate but permanent groundwater pollution.