Facile fabrication of Cu/kaolin nanocomposite as highly efficient heterogeneous catalyst for 4-nitrophenol reduction in aqueous solution

Abstract

• Simple and fast synthesis of kaolin-supported copper nanoparticle in a single step. • Use of environment friendly support which is relatively low cost and highly abundant in nature. • Conversion of toxic organic pollutant (4-nitrophenol) to useful one (4-aminophenol). • Easy recovery of catalyst with the help of centrifugation because of solid support. Hazardous organic pollutants in industrial wastewaters are becoming a major global challenge that threatens life on earth and particularly poses a serious health risk to human beings. 4-Nitrophenol (4-NP) is a highly hazardous organic contaminant that has been extensively utilized across multiple industries, and their wastewater disposal into water streams leads to a higher accumulation of 4-NP. It is therefore important for both academia and industry to make catalysts that are cheap, very effective, good for the environment, easy to recover, and can be used more than once for reducing 4-NP in normal conditions. This paper reports the synthesis, characterization, and application of Cu/kaolin nanocomposite (NC) as an efficient heterogeneous catalyst for decomposing 4-NP, a model organic molecule. The catalyst was synthesized by incorporating a copper precursor into layered kaolin clay and directly reducing the metal precursor using sodium borohydride (NaBH 4 ). The morphology, structure, surface property, and interaction of the resulting Cu/kaolin NC were characterized by ultraviolet–visible spectroscopy, Fourier transform infrared spectroscopy, scanning electron spectroscopy/energy-dispersive X-ray spectroscopy, selected area electron diffraction, X-ray diffraction, and N 2 adsorption/desorption, and the results clearly demonstrated the growth of copper nanoparticles on the kaolin surface. It was discovered that the Cu nanoparticles (NPs) on the kaolin surface had a crystallite size of about 23.6 nm. The significance of Cu NPs and the high catalytic activity of the synthesized Cu/kaolin NC toward 4-NP reduction by NaBH 4 were evaluated by the catalytic reduction experiments. Among the different nanocomposites synthesized, 30-Cu/kaolin showed the highest catalytic activity for 4-NP reduction, with a reduction efficiency of over 99 % within 4 min with a pseudo-first-order rate constant, k app , of 1.23 min −1 . Furthermore, the reusability test indicated that Cu/kaolin NC can be reused for up to six runs efficiently without significant decrease in its catalytic performance, indicating the nanocomposite has excellent stability and great potential applications in industrial and agricultural wastewater treatment.