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review · Proceedings of the Institution of Mechanical Engineers Part C Journal of Mechanical Engineering Science

Fabrication techniques of polymeric nanocomposites: A comprehensive review

2021117 citationsKafr el-Sheikh University

In plain language

Polymer nanocomposites, where nanoparticles are dispersed in a polymer matrix to improve mechanical and thermophysical properties, serve critical applications in sectors such as automotive and aircraft manufacturing. Fabricating these materials requires methods that achieve uniform nanoparticle dispersion without aggregation. Common production methods include melt-mixing, standard mixing, in-situ polymerisation, electrospinning, and selective laser sintering. In melt-mixing, aggregation issues can be resolved using water, atomic layer deposition, or plasma-assisted mechanochemistry, whilst high-frequency sonication achieves similar dispersion improvements for standard mixing techniques. In-situ polymerisation yields thermodynamically stable nanocomposites, and electrospinning is particularly suitable for generating porous structures. Furthermore, selective laser sintering presents clear advantages in preventing nanoparticle agglomeration. Each fabrication route offers distinct working principles, advantages, and drawbacks depending on the desired composite characteristics and structural requirements.

Key takeaways

  • Melt-mixing, mixing, in-situ polymerisation, electrospinning, and selective laser sintering are the primary methods for fabricating polymer nanocomposites.
  • Water, atomic layer deposition, and plasma-assisted mechanochemistry successfully resolve nanoparticle aggregation in melt-mixing processes.
  • High-frequency sonication prevents nanoparticle clumping during standard mixing procedures.
  • In-situ polymerisation creates thermodynamically stable materials, whilst electrospinning is suitable for generating porous structures.
  • Selective laser sintering offers clear operational benefits for avoiding nanoparticle agglomeration.

Why it matters

Enhancing polymers with nanoparticles improves their mechanical and thermal performance for vital sectors, including aircraft, vehicles, water purification, and energy systems. Achieving these improvements depends on distributing nanoparticles evenly without clumping. Comparing the strengths and limitations of primary fabrication methods helps engineers select appropriate manufacturing routes to produce stable, high-performance materials for demanding industrial uses.

Commercialisation angle

The abstract highlights applications across the automotive and aircraft industries, alongside broader relevance to water treatment and energy conversion. Potential users include composite material manufacturers and industrial engineers seeking to eliminate nanoparticle aggregation. Because this work is a review detailing various fabrication processes, their advantages, and their limitations, it sits at an informational and comparative stage rather than introducing an immediately deployable proprietary product.

AI-generated from the published abstract. Always read the original work before citing.

Abstract

Nanotechnology is the key solution for many human problems such as energy conversion, water treatment, and material science. In composite materials, nanoparticles are dispersed in a matrix material such as metals, ceramics, or polymers to enhance their mechanical and thermophysical properties. Polymer nanocomposite materials found their applications in vital fields such as the automotive and aircraft industries. There are many techniques adopted to produce polymer nanocomposites, and they are summarized and discussed according to our best known in this paper. All techniques aim to produce nanocomposite materials with uniform dispersion and without aggregations. Melt-mixing, mixing, in-situ polymerization, electrospinning, and selective laser sintering techniques are the most commonly used techniques to produce polymer nanocomposite. The utilization of water, atomic layer deposition, and plasma-assisted mechanochemistry are found to eradicate the issue of nanoparticles aggregation for melt-mixing technique. Also, sonication with high frequencies plays the same role for mixing techniques. In-situ polymerization provides fabrication of nanocomposites that are thermodynamically stable. Electrospinning represents an effective method which is suitable for producing porous structures. In addition, fabrication of nanocomposites via selective laser sintering has obvious benefits to overcome the problem of aggregation. The working principles of each technique, including the advantages and disadvantages, are discussed.

Research topics

  • Polymer Nanocomposite Synthesis and Irradiation
  • Electrohydrodynamics and Fluid Dynamics
  • Electrospun Nanofibers in Biomedical Applications

Sustainable Development Goals

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DOI: 10.1177/09544062211055662

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