Correlation of microstructure with thermal and tensile creep properties of novel Sn-5Sb-0.5Cu alloy reinforced with Co particles for soldering applications

Abstract

Abstract The present research examined how cobalt microalloying additions of 0.25, 0.5, 0.75, and 1 weight percent affected the microstructural properties, thermal features, and tensile creep characteristics of eutectic Sn-5 wt% Sb- 0.5 wt% Cu (SSC) lead-free solder alloy. According to the results, cobalt additions of 0.25, 0.5, and 0.75 wt% did not affect SbSn phase but significantly refined β -Sn grains, facilitating the formation of fine fibers (Cu,Co) 6 Sn 5 together with plate-like CoSn 3 phases, and preventing the formation of Cu 6 Sn 5 phases. Furthermore, a large amount of cobalt (1 wt%) addition accumulated in the coarsening of the CoSn 3 phase. Additions of 0.25 wt% Co, 0.75 wt% Co, and 1 wt% Co did not affect the melting temperatures, but pasty ranges had been slightly lowered, which may enhance the thermal characteristics. Addition of 0.5 wt% Co had unfavorable effects on both melting point and pasty range. This has significant effects on solder reliability and electronic service performance. In terms of creep behavior, the SSC-0.75 wt% Co specimens displayed the highest creep resistance because of the fine dispersion of intermetallic compounds (IMCs) and extended the creep-rupture life to a level that is 3.0 times greater than the SSC baseline. Lower creep resistance was observed in SSC-0.25 wt% Co specimens, which was mostly due to the smaller volume fraction of the precipitate phases and the absence of the CoSn 3 phase. Depending on the determined stress exponents and activation energies, it is suggested that the dominant deformation mechanism in SSC- x Co solders is the dislocation climb controlled by short-circuit pipe diffusion across the whole temperature range that was examined.