Adsorptive removal of malachite green dye from aqueous solution using Cordia africana leaf as biosorbent

Abstract

Abstract An untreated biosorbent derived from the leaves of Cordia africana was utilized in this study for the first time to remove malachite green (MG) dye from aqueous solutions via batchwise adsorption. Comprehensive characterizations of the biosorbent were conducted, including Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), and determination of the pH point of zero charge (pHpzc). The adsorption process was investigated under varying operational conditions: biosorbent dosage (0.25–0.65 g/100 mL), contact time (25–50 min), initial pollutant concentration (15–45 mg/L), and solution pH (4–9). Kinetic and isothermal models were employed to evaluate the adsorption mechanism. Characterization revealed an amorphous, heterogeneous surface. The biosorbent achieved an impressive MG removal efficiency of 98.9%, with a maximum Langmuir adsorption capacity ( Q max ) of 6.25 mg/g, indicating a monolayer chemisorption process in agreement with Langmuir and pseudo-second-order kinetics models. This study highlights the cost-effectiveness and potential of Cordia africana leaf-based biosorbent as a sustainable and efficient solution for the decolorization of MG-laden industrial effluents, providing a pathway for practical, large-scale applications.