Activated Carbon Functionalized with Nanoparticles: Ag and CuO for Antibacterial Water Treatment and Fe3O4 for Phosphate Adsorption

Abstract

Freshwater contamination by phosphate and pathogenic bacteria requires low-cost multifunctional treatment materials. Unlike previous studies that use a single biogenic agent to synthesize a single nanoparticle type, this work uses one fixed Aloe vera extraction protocol to generate three chemically distinct nanoparticles (Ag, CuO, Fe3O4) on the same waste-derived carbon support, enabling a direct, extract-controlled comparison of nanoparticle identity on water-treatment performance. Activated carbon (AC) was prepared from waste wattle bark (Acacia mearnsii) by steam activation at 700 °C and functionalized with biogenically synthesized Ag, CuO, and Fe3O4 nanoparticles (NPs) using Aloe vera extract as a reducing and stabilizing agent. Average nanoparticle sizes were 43 nm for Ag, 59 nm for CuO, and 13 nm for Fe3O4. FTIR, PXRD, SEM-EDS, TEM, DLS, TGA, and BET analysis characterized the materials. Among the composites, Fe3O4NPs/AC showed the best phosphate removal performance, achieving 93% removal and a maximum adsorption capacity of 9.3 mg/g under acidic conditions, compared with 3.3 mg/g for pristine AC. Equilibrium data were better described by the Freundlich model (R2 = 0.999), indicating adsorption on a heterogeneous surface. Ag NPs/AC exhibited complete inactivation of both Escherichia coli and Staphylococcus aureus within 2 h, while CuO NPs/AC (a more economical alternative) achieved near-complete inactivation of both bacteria within 6 h. AC from spent wattle bark and functionalized with green-synthesized nanoparticles is thus a promising platform for combined phosphate removal and antibacterial water treatment. Consistent with their respective roles, Fe3O4 NPs/AC was evaluated exclusively for phosphate adsorption, while Ag NPs/AC and CuO NPs/AC were evaluated exclusively for antibacterial activity; no single composite was tested for both functions.