Acid-activated corn silk as a promising phytosorbent for uptake of Malachite green and Cd (II) ion from simulated wastewater: equilibrium, kinetic and thermodynamic studies

Abstract

Malachite green (MG) dye and cadmium metal ion are toxic pollutants that should be removed from aqueous environment. The recent study aimed to examine the adsorption behavior of MG dye and Cd (II) from wastewater onto low-cost adsorbent prepared by activating corn silk with nitric acid (ACS) and characterized by SEM, FTIR, XRD, BET and TGA. The optimum MG and Cd (II) adsorption was observed at pH 7 and pH 9 and maximum uptake of both pollutants was at 0.5 g dosage, 60 mins contact time and 20 mg/L initial concentration. The retention of dye and metal ion by the studied adsorbent was best fit to Langmuir isotherm and Pseudo-second order kinetics. The maximum monolayer coverage capacity of ACS for MG dye and Cd (II) ion was 18.38 mg/g and 25.53 mg/g, respectively. Thermodynamic studies predicted a spontaneous reaction with exothermic process for MG dye whereas an endothermic and spontaneous process was confirmed for Cd ion based on estimated parameters. The adsorption mechanism of MG dye and Cd (II) uptake was by combination of electrostatic interaction, pore diffusion, ion exchange, pie-pie attraction, hydrogen bonding, and complexation. The adsorbed pollutants were effectively desorbed with significant regeneration efficiency after successive five cycles that proved the potential of low-cost biosorbent for selective sequestration of cationic dye and divalent metal ion from effluents.